Search results for " fuel cell"
showing 10 items of 169 documents
Impact of Ir modification on the durability of FeNC catalysts under start-up and shutdown cycle conditions
2022
A common problem associated with FeNC catalysts is their poor stability dominated by the carbon oxidation reaction (COR). In this work, the feasibility of stabilizing FeNC catalysts with small quantities of Ir was explored. With iridium being present, instead of COR the oxygen evolution reaction should be favored. The impact on structure and morphology was investigated by 57Fe Mössbauer spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy and transmission electron microscopy. The catalytic activity and durability for the oxygen reduction reaction was evaluated by rotating ring disc electrode experiments and accelerated stress tests mimicking the start-up and shutdown cycle (SS…
Ab initio thermodynamic study of (Ba,Sr)(Co,Fe)O3 perovskite solid solutions for fuel cell applications
2013
(Ba,Sr)(Co,Fe)O3 (BSCF) perovskite solid solutions are promising materials for solid oxide fuel cell cathodes and oxygen permeation membranes. Cathode performance strongly depends on the morphology of these materials remaining as a single phase or two-phase mixture. Combining ab initio calculations of the atomic and electronic structure of different supercells with thermodynamics of solid solutions, we have constructed and discussed phase diagrams of several important BSCF chemical compositions. It is demonstrated that in BSC cobaltite solid solution the spinodal decomposition may occur already at relatively low temperatures, while ferrite (BSF and SCF) solid solutions decompose at relative…
The Membrane-Less Microbial Fuel Cell (ML-MFC) with Ni-Co and Cu-B Cathode Powered by the Process Wastewater from Yeast Production
2020
Research related to measurements of electricity production was combined with parallel wastewater parameter reduction in a membrane-less microbial fuel cell (ML-MFC) fed with industry process wastewater (from a yeast factory). Electrodes with Ni–Co and Cu–B catalysts were used as cathodes. A carbon electrode (carbon cloth) was used as a reference due to its widespread use. It was demonstrated that all analyzed electrodes could be employed as cathodes in ML-MFC fed with process wastewater from yeast production. Electricity measurements during ML-MFC operations indicated that power (6.19 mW) and current density (0.38 mA·cm−2) were the highest for Ni–Co electrodes. In addition, during the explo…
Double cross-linked polyetheretherketone proton exchange membrane for fuel cell
2012
Abstract The proton exchange membrane based on polyetheretherketone was prepared via two steps of cross-linking. The properties of the double cross-linked membrane (water uptake, proton conductivity, methanol permeability and thermal stability) have been investigated for fuel cell applications. The prepared membrane exhibited relatively high proton conductivity, 3.2 × 10 −2 S cm −1 at room temperature and 5.8 × 10 −2 S cm −1 at 80 °C. The second cross-linking significantly decreased the water uptake of the membrane. The performance of direct methanol fuel cell was slightly improved as compared to Nafion ® 117 due to its low methanol permeability. The results indicated that the double cros…
Metallic interconnects for solid oxide fuel cell: Effect of water vapour on oxidation resistance of differently coated alloys
2009
International audience; The need of interconnect to separate fuel and oxidant gasses and connect individual cells into electrical series in a SOFC stack appears as one of the most important point in fuel cell technology. Due to their high electrical and thermal conductivities, thermal expansion compatibility with the other cell components and lowcost, ferritic stainless steels (FSS) are nowconsidered to be among the most promising candidate materials as interconnects in SOFC stacks. Despite the formation at 800 ◦C of a protective chromia Cr2O3 scale, it can transform in volatile chromium species, leading to the lost of its protectiveness and then the degradation of the fuel cell. A previous…
Analysis of the possibility of using stainless steel and copper boride alloy as catalyst for microbial fuel cell fuel electrode= Analiza możliwości z…
2015
wytwarzania energii elektrycznej z substancji odpadowych, jak i technologii oczyszczania ścieków. Ogniwa te charakteryzują się niskimi kosztami inwestycyjnymi. Ze względu na znakomite własności katalityczne, w wysokowydajnych ogniwach paliwowych (np. wodorowo-tlenowych), jako katalizator stosowana jest platyna. Jednak koszt platyny praktycznie uniemożliwia stosowanie jej w MFC. Z tego względu należy poszukiwać innych katalizatorów nie zawierających metali szlachetnych. W mikrobiologicznych ogniwach paliwowych najczęściej stosuje się elektrody grafitowe. Praca przedstawia analizę możliwości wykorzystania stali nierdzewnej oraz stopu Cu-B jako katalizatora elektrody paliwowej w mikrobiologicz…
Strontium and iron-doped barium cobaltite prepared by solution combustion synthesis: exploring a mixed-fuel approach for tailored intermediate temper…
2013
Ba0.5Sr0.5Co0.8Fe0.2O3-? (BSCF) powders were prepared by solution combustion synthesis using single and double fuels. The effect of the fuel mixture on the main properties of this well-known solid oxide fuel cell cathode material with high oxygen ion and electronic conduction was investigated in detail. Results showed that the fuel mixture significantly affected the area-specific resistance of the BSCF cathode materials, by controlling the oxygen deficiency and stabilizing the Co2+ oxidation state. It was demonstrated that high fuel-to-metal cations molar ratios and high reducing power of the combustion fuel mixture are mainly responsible for the decreasing of the area-specific resistance o…
Effect of mode of operation, substrate and final electron acceptor on single-chamber membraneless microbial fuel cell operating with a mixed community
2018
Abstract Waste minimization and circular thinking are to be achieved in order to cope with the limited amount of resources of our planet. In this perspective, bio-electrochemical systems (BESs) can contribute to the global balance with their ability to extract chemical residual energy from wastewater and transform it directly into electrical current. BESs development has been limited by the cost connected to reactor design, in which membranes and cathode catalyst constituted a major drawback. In this paper we report the optimization process of a simple reactor without membranes or precious catalyst that produced 47.1 mW m−2, which is more than what achieved with configurations including mem…
Influence of the methodology of inoculation in the performance of air-breathing microbial fuel cells
2017
In this work, four air-breathing microbial fuel cells (AB-MFC) were operated for 1 month in order to determine if the methodology of inoculation affects the steady-state performance of this type of MFCs. For this purpose, anaerobic and aerobic sludge were fed to two identical AB-MFCs without any external carbon source into a tight sealed environment during the first three days of start-up. For comparison purposes, other two AB-MFCs were operated mixing the initial sludge and an amount of sodium acetate as substrate. Results point out that the inoculation procedure does not affect the steady-state treatment capacity of the cells but it affects very seriously the production of electricity. On…
Load match and grid interaction optimization of a net zero energy building through electricity storage: An Italian case-study
2016
The study aims at applying of Load Match and Grid Interaction indexes to a Net Zero Energy Building in order to optimize the performances of its energy systems. The case study is a modular prefabricated house that uses solar energy (photovoltaic) and natural gas (Fuel Cell) as energy sources and equipped with an Energy Management System addressing the optimal energy use.